Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Luminescent properties of divalent samarium-doped strontium hexaborate | |
其他题名 | 论文其他题名 |
Zeng Q. H.; Pei Z. W.; Wang S. B.; Su Q.; Lu S. Z. | |
1999 | |
发表期刊 | Chemistry of Materials
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ISSN | 0897-4756 |
卷号 | 11期号:3页码:605-611 |
摘要 | The valence change of samarium from trivalent to divalent in strontium hexaborate (SrB6O10) prepared in air is observed. The temperature dependence of the luminescence and vibronic transitions of Sm2+ are studied. The Sm2+ ions occupy three crystallographic sites. With increasing temperature, the D-5(0)-->F-7(0) transition line exhibits red shifts, and the half-width increases. At room temperature, due to the thermal population through the 4f(5)5d channel, the D-5(1)-->F-7(J) transitions are observed even though the vibrational energy is very close to the energy gap between the D-5(1) and D-5(0) levels in the host. A coupled phonon energy of about 108 cm(-1) is determined from the vibronic transitions of Sm2+ in the host. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/25297 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Zeng Q. H.,Pei Z. W.,Wang S. B.,et al. Luminescent properties of divalent samarium-doped strontium hexaborate[J]. Chemistry of Materials,1999,11(3):605-611. |
APA | Zeng Q. H.,Pei Z. W.,Wang S. B.,Su Q.,&Lu S. Z..(1999).Luminescent properties of divalent samarium-doped strontium hexaborate.Chemistry of Materials,11(3),605-611. |
MLA | Zeng Q. H.,et al."Luminescent properties of divalent samarium-doped strontium hexaborate".Chemistry of Materials 11.3(1999):605-611. |
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